Tuning the Ease of Formation of On-Surface Metal-Adatom Coordination Polymers Featuring Diketones

dc.contributor.author Papageorgiou, Anthoula C.
dc.contributor.author Li, Jiang
dc.contributor.author Oh, Seung Cheol
dc.contributor.author Zhang, Bodong
dc.contributor.author Sağlam, Özge
dc.contributor.author Guo, Yuanyuan
dc.contributor.author Reichert, Joachim
dc.date.accessioned 2023-06-16T14:18:40Z
dc.date.available 2023-06-16T14:18:40Z
dc.date.issued 2018
dc.description.abstract We use pyrene-4,5,9,10-tetraketone molecules with substituents of varying bulkiness in the 2,7 positions to probe the generality and versatility of the previously reported on-surface coordination of two diketones with a single metal atom, leading to one-dimensional coordination polymers. Three different low index surfaces of group 11 metals (Cu, Ag and Au) are used to provide both the support and the metal atoms for metal-organic coordination. By real space visualisation with single molecule resolution employing scanning tunnelling microscopy we investigate the molecular self-assembly and show how this can be substantiated with the formation of metal-organic linear and cyclic oligomers, depending on the employed substrate. en_US
dc.description.sponsorship European Union's Horizon research and innovation programme [664878]; ERC Advanced Grant MolArt [247299]; Excellence Cluster Munich-Centre for Advanced Photonics (MAP); German Research Foundation (DFG) via the German Excellence Initiative; China Scholarship Council (CSC); Marie Curie International Incoming Fellowship (Project NANOULOP); TUM University Foundation Fellowship (TUFF); Basque Science Foundation for Science (Ikerbasque); POLYMAT; University of the Basque Country (SGIker) [GIU17/054]; Deutsche Forschungsgemeinschaft [MA 5215/4-1]; Gobierno de Espana (Ministerio de Economia y Competitividad) [CTQ2015-71936-REDT, CTQ2016-77970-R]; Gobierno Vasco [PC2015-1-01(06-37)]; Diputacion Foral de Guipuzcoa [OF215/2016]; European Union (ERA Chemistry, Marie Curie Career Integration) [618247]; European Research Council (ERC) under the European Union's Horizon research and innovation programme [722951]; DFG priority programme 1928 COORNETS; Gobierno Vasco (BERC program) en_US
dc.description.sponsorship This work has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement no 664878 and was further aided by the ERC Advanced Grant MolArt (No. 247299), the Excellence Cluster Munich-Centre for Advanced Photonics (MAP) funded by the German Research Foundation (DFG) via the German Excellence Initiative and the DFG priority programme 1928 COORNETS. L. J. and B. Z. were funded by the China Scholarship Council (CSC). O. S. and Y. G. were recipients of a Marie Curie International Incoming Fellowship (Project NANOULOP) and a TUM University Foundation Fellowship (TUFF), respectively. A. M. A. acknowledges support from the Basque Science Foundation for Science (Ikerbasque), POLYMAT, the University of the Basque Country (SGIker, Grupo de Investigacion GIU17/054), the Deutsche Forschungsgemeinschaft (MA 5215/4-1), Gobierno de Espana (Ministerio de Economia y Competitividad, CTQ2015-71936-REDT and CTQ2016-77970-R), Gobierno Vasco (BERC program and PC2015-1-01(06-37)), Diputacion Foral de Guipuzcoa (OF215/2016(ES)), the FP7 framework program of the European Union (ERA Chemistry, Marie Curie Career Integration Grant No. 618247 (NIRVANA)) and the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (grant agreement no. 722951). en_US
dc.identifier.doi 10.1039/c8nr02537a
dc.identifier.issn 2040-3364
dc.identifier.issn 2040-3372
dc.identifier.uri https://doi.org/10.1039/c8nr02537a
dc.identifier.uri https://hdl.handle.net/20.500.14365/1522
dc.language.iso en en_US
dc.publisher Royal Soc Chemistry en_US
dc.relation.ispartof Nanoscale en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Organic Coordination en_US
dc.subject Complex en_US
dc.subject Pyrene en_US
dc.subject Dehydrogenation en_US
dc.subject Hexahydroxytriphenylene en_US
dc.subject Transformations en_US
dc.subject Stabilization en_US
dc.subject Frameworks en_US
dc.subject Chemistry en_US
dc.subject Cu(111) en_US
dc.title Tuning the Ease of Formation of On-Surface Metal-Adatom Coordination Polymers Featuring Diketones en_US
dc.type Article en_US
dspace.entity.type Publication
gdc.author.id Cortizo-Lacalle, Diego/0000-0002-7382-2422
gdc.author.id Mateo-Alonso, Aurelio/0000-0002-5316-2594
gdc.author.id Papageorgiou, Anthoula C./0000-0003-1054-0097
gdc.author.id Saglam, Ozge/0000-0002-5583-3662
gdc.author.id BARTH, Johannes V/0000-0002-6270-2150
gdc.author.wosid Guo, Yuan/HKV-9606-2023
gdc.author.wosid Cortizo-Lacalle, Diego/C-6005-2013
gdc.author.wosid Papageorgiou, Anthoula C./O-8325-2016
gdc.author.wosid Mateo-Alonso, Aurelio/A-8600-2010
gdc.author.wosid Saglam, Ozge/AAB-3878-2020
gdc.author.wosid BARTH, Johannes V/E-4060-2013
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gdc.description.department İzmir Ekonomi Üniversitesi en_US
gdc.description.departmenttemp [Papageorgiou, Anthoula C.; Li, Jiang; Oh, Seung Cheol; Zhang, Bodong; Saglam, Oezge; Guo, Yuanyuan; Reichert, Joachim; Barth, Johannes V.] Tech Univ Munich, Phys Dept E20, D-85748 Garching, Germany; [Belen Marco, A.; Cortizo-Lacalle, Diego; Mateo-Alonso, Aurelio] Univ Basque Country UPV EHU, POLYMAT, Ave Tolosa 72, E-20018 Donostia San Sebastian, Spain; [Mateo-Alonso, Aurelio] Basque Fdn Sci, Ikerbasque, Bilbao, Spain; [Saglam, Oezge] Izmir Univ Econ, Fac Engn, Sakarya Cad 156, Izmir, Turkey; [Guo, Yuanyuan] Aarhus Univ, Interdisciplinary Nanosci Ctr INANO, DK-8000 Aarhus, Denmark en_US
gdc.description.endpage 9568 en_US
gdc.description.issue 20 en_US
gdc.description.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
gdc.description.scopusquality Q1
gdc.description.startpage 9561 en_US
gdc.description.volume 10 en_US
gdc.description.wosquality Q1
gdc.identifier.openalex W2797113118
gdc.identifier.pmid 29745943
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gdc.virtual.author Sağlam, Özge
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