Browsing by Author "Kavaz, E."

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Citation - WoS: 4
Citation - Scopus: 5
First Exploration of Pr6o11 Nanoparticle Integration in Borotellurite Glasses: Synthesis, Characterization, and Performance for Enhanced Mechanical Strength and Radiation Shielding
(Elsevier Sci Ltd, 2025) Kilic, G.; Ilik, E.; Kavaz, E.; Durmus, Hasan; Guler, Omer; Birdogan, Selcuk; Tekin, H. O.
This study investigates the incorporation of Pr6O11 nanoparticles into lithium borotellurite glass matrices to enhance their mechanical and radiation shielding properties. Glass compositions, synthesized with varying Pr6O11 concentrations from 0 to 8 mol%, exhibited increasing densities from 4.00783 g cm- 3 to 4.94440 g cm-3 and reduced molar volumes, confirming nanoparticle-induced densification. X-ray diffraction analysis revealed amorphous structures with shifts in the hollow band indicating compact network rearrangements. Scanning electron microscopy and energy-dispersive X-ray analyses confirmed homogeneous Pr distribution up to 6 mol%, with clustering observed in 8 mol% samples. Vickers' microhardness values progressively increased, highlighting enhanced mechanical strength due to reduced non-bridging oxygen ions and network cross-linking. Gamma-ray shielding experiments demonstrated superior performance of the 8 mol% sample (Pr8), with the highest mass attenuation coefficients, effective atomic number, and reduced half-value layer. Neutron attenuation assessments further confirmed improved shielding capabilities, with Pr8 achieving the highest effective removal crosssection. In conclusion, Pr6O11-doped lithium borotellurite glasses demonstrate significant potential for advanced radiation shielding applications.
Citation - WoS: 2
Citation - Scopus: 2
Impact of Controlled Oxidation and Incorporation of High Entropy Rare-Earth Alloys (HE-REAs) on the Structural, Physical, Optical, and Radiation Shielding Performance of Zinc-Borate Glasses
(Elsevier Ltd, 2025) Ilik, E.; Guler, Seval Hale; Guler, Omer; Durmus, Hasan; Kavaz, E.; Birdogan, Selcuk; Tekin, H. O.
This study investigates the influence of high entropy oxide (HEO) and high entropy alloy oxide (HEAO) dopants on the structural, optical, and radiation shielding properties of zinc-borate glasses. Two synthesis routes were employed through direct mechanical alloying of five rare-earth oxides such as Sm2O3, Ho2O3, Er2O3, Yb2O3, Gd2O3 to form (SmHoErYbGd)2O3 HEO, and mechanical alloying of the corresponding rare-earth metals followed by oxidation to produce HEAO of the same elemental composition. The central hypothesis proposed that the dopant structure and oxygen coordination, not just elemental presence, critically influence the on characteristic behaviors in terms of radiation attenuation. Structural analyses confirmed that HEAO-doped glasses exhibit more homogeneous, amorphous networks. Optical characterizations revealed red-shifted absorption edges and lower Urbach energies in HEAO samples, indicating reduced disorder. HEAO-doped glasses showed superior gammaray shielding, with higher linear attenuation coefficients and lower half-value layers than HEO or undoped samples. Most notably, HEAO glass achieved the highest fast neutron removal cross-section, surpassing water, graphite, and B4C. These findings demonstrate that rare-earth high entropy alloy oxides offer a structurally optimized pathway for designing next-generation multifunctional glasses for radiation-related applications.
Structural Evolution and Dual Γ-Neutron Shielding Performance of Nano-Gd2o3 Reinforced Lithium Borotellurite Glasses
(Elsevier, 2026) Durmus, Hasan; Kilic, G.; Ilik, E.; Kavaz, E.; Guler, Omer; Birdogan, Selcuk; Tekin, H. O.
This study investigates the structural, physical, and radiation-shielding properties of nano-Gd2O3-reinforced lithium borotellurite glasses with the composition 50TeO2-30B2O3-(20-x)Li2O-xGd2O3 (x= 0-10 mol %). X-ray diffraction and transmission electron microscopy confirmed the fully amorphous nature of the glasses and the homogeneous distribution of nanoscale Gd clusters. Density increased from 4.03 to 4.77 g/cm3, accompanied by compositional shifts, decreasing boron and increasing oxygen and tellurium contents, indicating enhanced structural compactness and electron density. Gamma-ray attenuation measurements revealed a 74 % increase in the linear attenuation coefficient from 8.33 to 14.53 cm-1 at 81 key and a nearly 27 % reduction in the half-value layer from 1.21 to 0.89 cm. Effective atomic number values remained highest for Gd(n)10 across the photon energy range investigated. Experimental neutron dose measurements showed absorption improvements from 37.66 % to 51.91 %, while the effective removal cross-section increased from 0.1066 to 0.1096 cm-1, outperforming water, B4C, and graphite. Compared with the Gd-doped zinc borotellurite glasses reported in the literature, the present lithium-based system exhibited higher densification and superior dual gamma-neutron attenuation. These results demonstrate that controlled nano-Gd2O3 integration into the lithium borotellurite matrix yields a stable, lead-free amorphous material with outstanding radiation-shielding efficiency for advanced photonic and nuclear applications.