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Browsing by Author "Kilic, G."

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    Citation - WoS: 4
    Citation - Scopus: 5
    First Exploration of Pr6o11 Nanoparticle Integration in Borotellurite Glasses: Synthesis, Characterization, and Performance for Enhanced Mechanical Strength and Radiation Shielding
    (Elsevier Sci Ltd, 2025) Kilic, G.; Ilik, E.; Kavaz, E.; Durmus, Hasan; Guler, Omer; Birdogan, Selcuk; Tekin, H. O.
    This study investigates the incorporation of Pr6O11 nanoparticles into lithium borotellurite glass matrices to enhance their mechanical and radiation shielding properties. Glass compositions, synthesized with varying Pr6O11 concentrations from 0 to 8 mol%, exhibited increasing densities from 4.00783 g cm- 3 to 4.94440 g cm-3 and reduced molar volumes, confirming nanoparticle-induced densification. X-ray diffraction analysis revealed amorphous structures with shifts in the hollow band indicating compact network rearrangements. Scanning electron microscopy and energy-dispersive X-ray analyses confirmed homogeneous Pr distribution up to 6 mol%, with clustering observed in 8 mol% samples. Vickers' microhardness values progressively increased, highlighting enhanced mechanical strength due to reduced non-bridging oxygen ions and network cross-linking. Gamma-ray shielding experiments demonstrated superior performance of the 8 mol% sample (Pr8), with the highest mass attenuation coefficients, effective atomic number, and reduced half-value layer. Neutron attenuation assessments further confirmed improved shielding capabilities, with Pr8 achieving the highest effective removal crosssection. In conclusion, Pr6O11-doped lithium borotellurite glasses demonstrate significant potential for advanced radiation shielding applications.
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    Citation - WoS: 1
    GPR Raw-Data Analysis to Detect Crack Using Order Statistic Filtering
    (ASTM International, 2016) Kilic, G.; Ünlütürk, M.S.
    Ground penetrating radar (GPR) uses data collected with the aid of electromagnetic waves transmitted into a structure by antenna to assess and monitor the structural health of many different kinds of civil infrastructure. With GPR technology promoting their system with promises of the achievement of in excess of 1000 sample points per scan, this research demonstrated on the basis of the Nyquist theorem that 256 sample points per scan provided equally reliable inspection results. Furthermore, 256 sample points per scan GPR data were further analyzed by order statistic filtering with neural networks to locate cracks within concrete materials. The results showed that the neural network order statistic filters are effective in their use of detecting cracks in noisy environments using 256 sample points per scan GPR data. © 2017 Elsevier B.V., All rights reserved.
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    Mechanical Properties of Acropora Cervicornis Aragonite Skeleton by Using Multiscale Models Based on Micro-CT Data
    (Sage Publications Inc, 2024) Altintas, G.; Cankal, D.; Kilic, G.; Ergun, S.
    Corals, crucial for ocean ecosystems, face threats such as ocean acidification from global warming and pollution, which weaken their skeletons. This study focuses on Acropora cervicornis, known for its hard but fragile structure, requiring strength and flexibility to withstand the forces from climate-driven atmospheric events. An experiment using uniaxial mechanical loading from the initial stage to complete failure at a very low strain rate (1.2821 × 10−5 s−1) was conducted to ascertain the mechanical properties of corals. The geometric properties and Young's modulus were analysed based on various levels of micro-architectural details from micro-CT data, with resolution values influencing the measurements. The highest resolution model showed a Young's modulus approaching 22.265 GPa and porosity at 40.448%. Calibration of finite element models incorporating micro-architectural details enabled a precise comparison of parameter effects and more accurate results, highlighting the significance of resolution in modelling coral mechanical properties. © The Author(s) 2024.
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    Citation - Scopus: 1
    Nanoarchitectonics and Radiation Mitigation in Sm2O3-Doped Lithium Borotellurite Glass Systems: From Amorphous Harmony To Localized Order
    (Elsevier B.V., 2025) Kilic, G.; Durmus, Hasan; Birdogan, Selcuk; Ilik, E.; Perisanoglu, Esra Kavaz; Saltik, Sevda; Tekin, H. O.
    In this study, a novel series of nano-Sm2O3-doped lithium borotellurite glasses was synthesized and systematically investigated in terms of their structural, physical, and radiation shielding characteristics. X-ray diffraction confirmed the amorphous nature of all samples, while transmission electron microscopy revealed progressive nanoarchitectural refinement and particle growth with increasing Sm2O3 content, from uniformly dispersed nanodomains to dense agglomerates exhibiting short-range crystalline ordering. Energy-dispersive X-ray spectroscopy and elemental mapping validated the homogeneous incorporation of boron, oxygen, tellurium, and samarium throughout the glass matrix without phase separation. Gamma-ray shielding evaluations showed enhanced mass attenuation coefficients and reduced half-value layers, particularly in the Sm(n)8 sample, with significant performance gains at lower photon energies. Neutron shielding assessments further indicated elevated macroscopic removal cross-section values and dose attenuation, affirming the compositional benefit of Sm2O3 for fast neutron mitigation. It can be concluded that nano-Sm2O3 incorporation would play a multifunctional role on structural and radioprotective properties in addition to morphostructural features of lithium borotellurite glasses.
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    Structural Evolution and Dual Γ-Neutron Shielding Performance of Nano-Gd2o3 Reinforced Lithium Borotellurite Glasses
    (Elsevier, 2026) Durmus, Hasan; Kilic, G.; Ilik, E.; Kavaz, E.; Guler, Omer; Birdogan, Selcuk; Tekin, H. O.
    This study investigates the structural, physical, and radiation-shielding properties of nano-Gd2O3-reinforced lithium borotellurite glasses with the composition 50TeO2-30B2O3-(20-x)Li2O-xGd2O3 (x= 0-10 mol %). X-ray diffraction and transmission electron microscopy confirmed the fully amorphous nature of the glasses and the homogeneous distribution of nanoscale Gd clusters. Density increased from 4.03 to 4.77 g/cm3, accompanied by compositional shifts, decreasing boron and increasing oxygen and tellurium contents, indicating enhanced structural compactness and electron density. Gamma-ray attenuation measurements revealed a 74 % increase in the linear attenuation coefficient from 8.33 to 14.53 cm-1 at 81 key and a nearly 27 % reduction in the half-value layer from 1.21 to 0.89 cm. Effective atomic number values remained highest for Gd(n)10 across the photon energy range investigated. Experimental neutron dose measurements showed absorption improvements from 37.66 % to 51.91 %, while the effective removal cross-section increased from 0.1066 to 0.1096 cm-1, outperforming water, B4C, and graphite. Compared with the Gd-doped zinc borotellurite glasses reported in the literature, the present lithium-based system exhibited higher densification and superior dual gamma-neutron attenuation. These results demonstrate that controlled nano-Gd2O3 integration into the lithium borotellurite matrix yields a stable, lead-free amorphous material with outstanding radiation-shielding efficiency for advanced photonic and nuclear applications.
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