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https://hdl.handle.net/20.500.14365/1522
Title: | Tuning the ease of formation of on-surface metal-adatom coordination polymers featuring diketones | Authors: | Papageorgiou, Anthoula C. Li, Jiang Oh, Seung Cheol Zhang, Bodong Sağlam, Özge Guo, Yuanyuan Reichert, Joachim |
Keywords: | Organic Coordination Complex Pyrene Dehydrogenation Hexahydroxytriphenylene Transformations Stabilization Frameworks Chemistry Cu(111) |
Publisher: | Royal Soc Chemistry | Abstract: | We use pyrene-4,5,9,10-tetraketone molecules with substituents of varying bulkiness in the 2,7 positions to probe the generality and versatility of the previously reported on-surface coordination of two diketones with a single metal atom, leading to one-dimensional coordination polymers. Three different low index surfaces of group 11 metals (Cu, Ag and Au) are used to provide both the support and the metal atoms for metal-organic coordination. By real space visualisation with single molecule resolution employing scanning tunnelling microscopy we investigate the molecular self-assembly and show how this can be substantiated with the formation of metal-organic linear and cyclic oligomers, depending on the employed substrate. | URI: | https://doi.org/10.1039/c8nr02537a https://hdl.handle.net/20.500.14365/1522 |
ISSN: | 2040-3364 2040-3372 |
Appears in Collections: | PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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