Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.14365/1522
Title: Tuning the ease of formation of on-surface metal-adatom coordination polymers featuring diketones
Authors: Papageorgiou, Anthoula C.
Li, Jiang
Oh, Seung Cheol
Zhang, Bodong
Sağlam, Özge
Guo, Yuanyuan
Reichert, Joachim
Keywords: Organic Coordination
Complex
Pyrene
Dehydrogenation
Hexahydroxytriphenylene
Transformations
Stabilization
Frameworks
Chemistry
Cu(111)
Publisher: Royal Soc Chemistry
Abstract: We use pyrene-4,5,9,10-tetraketone molecules with substituents of varying bulkiness in the 2,7 positions to probe the generality and versatility of the previously reported on-surface coordination of two diketones with a single metal atom, leading to one-dimensional coordination polymers. Three different low index surfaces of group 11 metals (Cu, Ag and Au) are used to provide both the support and the metal atoms for metal-organic coordination. By real space visualisation with single molecule resolution employing scanning tunnelling microscopy we investigate the molecular self-assembly and show how this can be substantiated with the formation of metal-organic linear and cyclic oligomers, depending on the employed substrate.
URI: https://doi.org/10.1039/c8nr02537a
https://hdl.handle.net/20.500.14365/1522
ISSN: 2040-3364
2040-3372
Appears in Collections:PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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