Dynamics of Spatially Confined Bisphenol a Trimers in a Unimolecular Network on Ag(111)
| dc.contributor.author | Lloyd, Julian A. | |
| dc.contributor.author | Papageorgiou, Anthoula C. | |
| dc.contributor.author | Fischer, Sybille | |
| dc.contributor.author | Oh, Seung Cheol | |
| dc.contributor.author | Saglam, Ozge | |
| dc.contributor.author | Diller, Katharina | |
| dc.contributor.author | Duncan, David A. | |
| dc.date.accessioned | 2023-06-16T14:11:55Z | |
| dc.date.available | 2023-06-16T14:11:55Z | |
| dc.date.issued | 2016 | |
| dc.description.abstract | Bisphenol A (BPA) aggregates on Ag(111) shows a polymorphism between two supramolecular motifs leading to formation of distinct networks depending on thermal energy. With rising temperature a dimeric pairing scheme reversibly converts into a trimeric motif, which forms a hexagonal superstructure with complex dynamic characteristics. The trimeric arrangements notably organize spontaneously into a self-assembled one-component array with supramolecular BPA rotors embedded in a two-dimensional stator sublattice. By varying the temperature, the speed of the rotors can be controlled as monitored by direct visualization. A combination of scanning tunneling microscopy and dispersion corrected density-functional tight-binding (DFTB-vdW(surf)) based molecular modeling reveals the exact atomistic position of each molecule within the assembly as well as the driving force for the formation of the supramolecular rotors. | en_US |
| dc.description.sponsorship | ERC Advanced Grant MolArt [247299]; Marie Curie Intra-European Fellowship (project NASUMECA) [274842]; Marie Curie International Incoming Fellowship (Project NANOULOP) [302157]; Alexander von Humboldt Foundation; Helmholtz-Zentrum Berlin (HZB) | en_US |
| dc.description.sponsorship | This work was enabled by the ERC Advanced Grant MolArt (No. 247299). A.C.P., O.S., and D.A.D. were supported by a Marie Curie Intra-European Fellowship (project NASUMECA, No. 274842), a Marie Curie International Incoming Fellowship (Project NANOULOP, No. 302157), and the Alexander von Humboldt Foundation, respectively. We thank Helmholtz-Zentrum Berlin (HZB) for the allocation of synchrotron radiation beamtime and financial support. | en_US |
| dc.identifier.doi | 10.1021/acs.nanolett.5b05026 | |
| dc.identifier.issn | 1530-6984 | |
| dc.identifier.issn | 1530-6992 | |
| dc.identifier.uri | https://doi.org/10.1021/acs.nanolett.5b05026 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14365/1503 | |
| dc.language.iso | en | en_US |
| dc.publisher | Amer Chemical Soc | en_US |
| dc.relation.ispartof | Nano Letters | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Self-assembly | en_US |
| dc.subject | rotor arrays | en_US |
| dc.subject | scanning tunneling microscopy | en_US |
| dc.subject | dispersion-corrected density-functional tight-binding | en_US |
| dc.subject | silver surface | en_US |
| dc.subject | Molecular Machines | en_US |
| dc.subject | Single-Molecule | en_US |
| dc.subject | Surfaces | en_US |
| dc.subject | Rotation | en_US |
| dc.title | Dynamics of Spatially Confined Bisphenol a Trimers in a Unimolecular Network on Ag(111) | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.id | Allegretti, Francesco/0000-0001-6141-7166 | |
| gdc.author.id | Saglam, Ozge/0000-0002-5583-3662 | |
| gdc.author.id | Papageorgiou, Anthoula C./0000-0003-1054-0097 | |
| gdc.author.id | Maurer, Reinhard J/0000-0002-3004-785X | |
| gdc.author.id | Reuter, Karsten/0000-0001-8473-8659 | |
| gdc.author.id | BARTH, Johannes V/0000-0002-6270-2150 | |
| gdc.author.id | Klappenberger, Florian/0000-0002-2877-6105 | |
| gdc.author.wosid | Allegretti, Francesco/G-5476-2016 | |
| gdc.author.wosid | Saglam, Ozge/AAB-3878-2020 | |
| gdc.author.wosid | Maurer, Reinhard J/A-4791-2013 | |
| gdc.author.wosid | Papageorgiou, Anthoula C./O-8325-2016 | |
| gdc.author.wosid | Reuter, Karsten/D-9442-2011 | |
| gdc.author.wosid | BARTH, Johannes V/E-4060-2013 | |
| gdc.author.wosid | Klappenberger, Florian/B-2590-2014 | |
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| gdc.description.department | İzmir Ekonomi Üniversitesi | en_US |
| gdc.description.departmenttemp | [Lloyd, Julian A.; Papageorgiou, Anthoula C.; Fischer, Sybille; Oh, Seung Cheol; Saglam, Ozge; Diller, Katharina; Duncan, David A.; Allegretti, Francesco; Klappenberger, Florian; Reichert, Joachim; Barth, Johannes V.] Tech Univ Munich, Phys Dept E20, D-85748 Garching, Germany; [Diller, Katharina; Stoehr, Martin; Maurer, Reinhard J.; Reuter, Karsten] Tech Univ Munich, Theoret Chem, D-85748 Garching, Germany; [Lloyd, Julian A.] Monash Univ, Dept Mat Engn, Clayton Campus, Clayton, Vic 3800, Australia; [Saglam, Ozge] Izmir Univ Econ, Fac Engn & Comp Sci, Sakarya Cad 156, Izmir, Turkey; [Diller, Katharina] Ecole Polytech Fed Lausanne, Inst Condensed Matter Phys, CH-1015 Lausanne, Switzerland; [Duncan, David A.] Diamond Light Source, Didcot OX11 0DE, Oxon, England; [Maurer, Reinhard J.] Yale Univ, Dept Chem, New Haven, CT USA | en_US |
| gdc.description.endpage | 1889 | en_US |
| gdc.description.issue | 3 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q1 | |
| gdc.description.startpage | 1884 | en_US |
| gdc.description.volume | 16 | en_US |
| gdc.description.wosquality | Q1 | |
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